Δ3-1, 3, 4-Oxadiazolines: Photochemical Precursors to Diazoalkanes and sec-Alkanediazonium Ions in Acidic Solution1

…, BD Wagner, CSQ Lew, J Warkentin…

Index: Pezacki; Wagner; Lew; Warkentin; Lusztyk Journal of the American Chemical Society, 1997 , vol. 119, # 7 p. 1789 - 1790

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Citation Number: 13

Abstract

Diazoalkanes and their conjugate acids, diazonium ions, are important reactive intermediates which have been implicated in the carcinogenicity and mutagenicity of N-alkyl- N-nitroso compounds. 2 Alkanediazoates have been studied extensively and have been shown to decompose via diazonium ion intermediates. 3 Nitrous acid deaminations of aliphatic amines are known to involve the same diazonium ion intermediates. 4, 5 It has ...