Reactivity of the perhaloalkanes CF2X2 (X= Cl, Br) with nucleophiles. 6. Coexistence of carbene and radical processes initiated by single electron transfer

I Rico, D Cantacuzene…

Index: Rixo, I.; Cantacuzene, D.; Wakselman, C. Journal of Organic Chemistry, 1983 , vol. 48, # 12 p. 1979 - 1982

Full Text: HTML

Citation Number: 46

Abstract

Conclusion The capabilities of the CAMEO program have been extended to include electrophilic and nucleophilic processes involving organosilicon intermediates. The unique reactivity and directing ability of silyl groups required modification to several parts of the program, including the perception of acidities, electrophiles, nucleophiles, and carbonium ion stabilities. In addition, the stereochemical sophistication of the program has been ...

(Diethylamino) sulfur trifluoride in organic synthesis. 2. The transformation of sulfoxides to. alpha.-fluoro thioethers

[McCarthy, James R.; Peet, Norton P.; LeTourneau, Micheal E.; Inbasekaran, Muthiah Journal of the American Chemical Society, 1985 , vol. 107, # 3 p. 735 - 737]

S RN 1 substitutions of halogenoperfluoroalkanes (CF 3 Br or CF 2 Cl 2) under pressure

[Wakselman, Claude; Tordeux, Marc Journal of the Chemical Society, Chemical Communications, 1984 , # 12 p. 793 - 794]

Difluoromethyl Phenyl Sulfone as a Selective Difluoromethylene Dianion Equivalent: One??Pot Stereoselective Synthesis of anti??2, 2??Difluoropropane??1, 3??diols

[Prakash, G. K. Surya; Hu, Jinbo; Mathew, Thomas; Olah, George A. Angewandte Chemie - International Edition, 2003 , vol. 42, # 42 p. 5216 - 5219]