A new route to α-fluoroalkylphosphonates

R Waschbüsch, J Carran, P Savignac

Index: Waschbuesch, Rachel; Carran, John; Savignac, Philippe Journal of the Chemical Society - Perkin Transactions 1, 1997 , # 8 p. 1135 - 1139

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Abstract

Several alkylated α-fluorophosphonates have been synthesized by the reaction of an alkyl iodide, bromide (or activated chloride) with a monofluorosilyllithium phosphonate species produced either from the reaction of butyllithium, phenyllithium or other alkyllithium reagent as base and trimethylsilyl chloride with a diethyl monofluoromethylphosphonate. A study of the reaction conditions with respect to the metallating agent, silylating agent and starting ...