Iron-Catalyzed Suzuki− Miyaura Coupling of Alkyl Halides

T Hatakeyama, T Hashimoto, Y Kondo…

Index: Hatakeyama, Takuji; Hashimoto, Toru; Kondo, Yoshiyuki; Fujiwara, Yuichi; Seike, Hirofumi; Takaya, Hikaru; Tamada, Yoshinori; Ono, Teruo; Nakamura, Masaharu Journal of the American Chemical Society, 2010 , vol. 132, # 31 p. 10674 - 10676

Full Text: HTML

Citation Number: 129

Abstract

In the presence of novel iron (II) chloride− diphosphine complexes and magnesium bromide, lithium arylborates react with primary and secondary alkyl halides to give the corresponding coupling products in good to excellent yields. High functional group compatibility is also demonstrated in the reactions of substrates possessing reactive substituents, such as alkoxycarbonyl, cyano, and carbonyl groups.

Related Articles:

Carbon-oxygen bond-cleavage reactions by electron transfer. 4. Electrochemical and alkali-metal reductions of phenoxynaphthalenes

[Thornton, Todd A.; Ross, Gerald A.; Patil, Dilip; Mukaida, Kenichi; Warwick, Jeffrey O.; et al. Journal of the American Chemical Society, 1989 , vol. 111, # 7 p. 2434 - 2440]

“Design” of Boron??Based Compounds as Pro??Nucleophiles and Co??Catalysts for Indium (I)??Catalyzed Allyl Transfer to Various Csp3??Type Electrophiles

[Dao, Hai Thanh; Schneider, Uwe; Kobayashi, Shu Chemistry - An Asian Journal, 2011 , vol. 6, # 9 p. 2522 - 2529]

Carbon-oxygen bond-cleavage reactions by electron transfer. 4. Electrochemical and alkali-metal reductions of phenoxynaphthalenes

[Thornton, Todd A.; Ross, Gerald A.; Patil, Dilip; Mukaida, Kenichi; Warwick, Jeffrey O.; et al. Journal of the American Chemical Society, 1989 , vol. 111, # 7 p. 2434 - 2440]

Carbon-oxygen bond-cleavage reactions by electron transfer. 4. Electrochemical and alkali-metal reductions of phenoxynaphthalenes

[Thornton, Todd A.; Ross, Gerald A.; Patil, Dilip; Mukaida, Kenichi; Warwick, Jeffrey O.; et al. Journal of the American Chemical Society, 1989 , vol. 111, # 7 p. 2434 - 2440]

Carbon-oxygen bond-cleavage reactions by electron transfer. 4. Electrochemical and alkali-metal reductions of phenoxynaphthalenes

[Thornton, Todd A.; Ross, Gerald A.; Patil, Dilip; Mukaida, Kenichi; Warwick, Jeffrey O.; et al. Journal of the American Chemical Society, 1989 , vol. 111, # 7 p. 2434 - 2440]

More Articles...