Acta Phys Chim Sin
Kinetics of Acid-Catalyzed Smiles Rearrangement of 2, 6-Dimethoxy-2-pyrimidinyloxy-N-arylbenzylamine Derivatives
PZ ZHANG, MJ YE, WL HU, J WU
Index: Yuan, Jun; Zhong, Ye; Li, Shiliang; Zhao, Xue; Luan, Guoqin; Zhao, Zhenjiang; Huang, Jin; Li, Honglin; Xu, Yufang Chinese Journal of Chemistry, 2013 , vol. 31, # 9 p. 1192 - 1198
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Abstract
The kinetics of the acid-catalyzed Smiles rearrangement reactions of 2, 6-dimethoxy-2- pyrimidinyloxy-N-arylbenzylamine derivatives was investigated. The effects of initial concentrations of hydrochloric acid, solvent, temperature, and substituent on reaction rates