Carboxylation of pincer PCP platinum methoxide complexes under formation of metalla carbonates
A Arunachalampillai, N Loganathan, OF Wendt
Index: Arunachalampillai, Athimoolam; Loganathan, Nagarajan; Wendt, Ola F. Polyhedron, 2012 , vol. 32, # 1 p. 24 - 29
Full Text: HTML
Citation Number: 8
Abstract
The ligand 2, 6-bis [(diphenylphosphino) methyl] benzene ((PCP) H) was prepared and characterised in an improved manner. With platinum it forms the complex (PCP) PtOTf which reacts with sodium methoxide to give (PCP) PtOMe as the major product together with a small amount of [(PCP) Pt] 2-μ-H. The platinum methoxide reacts with carbon dioxide to give (PCP) PtO (CO) OMe. Also the dinuclear [(PCP) Pt] 2 (μ-O (CO) OMe) is formed in this ...
Related Articles:
[Cohen, Revital; Van Der Boom, Milko E.; Shimon, Linda J. W.; Rozenberg, Haim; Milstein, David Journal of the American Chemical Society, 2000 , vol. 122, # 32 p. 7723 - 7734]
[Ashton, Peter R.; Calcagno, Patrizia; Spencer, Neil; Harris, Kenneth D. M.; Philp, Douglas Organic Letters, 2000 , vol. 2, # 10 p. 1365 - 1368]
[Kozhanov, Konstantin A.; Bubnov, Michael P.; Cherkasov, Vladimir K.; Vavilina, Nina N.; Efremova, Larisa Yu.; Artyushin, Oleg. I.; Odinets, Irina L.; Abakumov, Gleb A. Dalton Transactions, 2008 , # 21 p. 2849 - 2853]
[Ashton, Peter R.; Calcagno, Patrizia; Spencer, Neil; Harris, Kenneth D. M.; Philp, Douglas Organic Letters, 2000 , vol. 2, # 10 p. 1365 - 1368]
The facile cyclometallation reaction of 1, 3-bis [(diphenyl-phosphino) methyl] benzene
[Rimml, Heinrich; Venanzi, Luigi M. Journal of Organometallic Chemistry, 1983 , vol. 259, # 1 p. C6 - C7]