Reaction of cyclopropane carboxylic acid derivatives with sulphur tetrafluoride—an example of a diastereoselective ring opening

Z Hell, Z Finta, W Dmowski, F Faigl, YM Pustovit…

Index: Hell; Finta; Dmowski; Faigl; Pustovit; Toke; Harmat Journal of Fluorine Chemistry, 2000 , vol. 104, # 2 p. 297 - 301

Full Text: HTML

Citation Number: 7

Abstract

Cyclopropane carboxylic acid derivatives can be converted into trifluoromethyl group- containing compounds using SF4. In the case of a bicyclic cyclopropane carboxylic acid lactone, similar treatment with sulphur tetrafluoride resulted in the cyclopropane ring opening in a diastereoselective manner.

Related Articles:

Synthesis of 2, 3-dihydro-1H-pyrrolo [1, 2-a] benzimidazoles via the cyclopropyliminium rearrangement of substituted 2-cyclopropylbenzimidazoles

[Salikov, Rinat F.; Platonov, Dmitry N.; Frumkin, Aleksandr E.; Lipilin, Dmitry L.; Tomilov, Yury V. Tetrahedron, 2013 , vol. 69, # 16 p. 3495 - 3505]

More Articles...