Enantio??and Diastereoselective Iodocyclopropanation of Allylic Alcohols by Using a Substituted Zinc Carbenoid

LPB Beaulieu, LE Zimmer…

Index: Beaulieu, Louis-Philippe B.; Zimmer, Lucie E.; Charette, Andr B. Chemistry - A European Journal, 2009 , vol. 15, # 44 p. 11829 - 11832

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Citation Number: 18

Abstract

In addition to being present in several bioactive natural products,[1] 1, 2, 3-trisubstituted cyclopropanes embed significant structural complexity that has prompted their use as peptidomimetics,[2] and as substrates for various organic and organometallic reactions.[3] 2, 3-Disubstituted iodocyclopropanes have been shown to be versatile precursors to access a multitude of highly functionalized cyclopropane units.[4] However, few methods for their ...

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