Surface-catalyzed hydrochlorination of alkenes. The reaction of the gases hydrogen chloride and 1, 3-butadiene

LM Mascavage, H Chi, S La…

Index: Mascavage, Linda M.; Chi, Hongji; La, Sangmoo; Dalton, David R. Journal of Organic Chemistry, 1991 , vol. 56, # 2 p. 595 - 601

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Citation Number: 7

Abstract

Mixtures of gaseous hydrogen chloride and gaseous l, &butadiene at total pressures less than 1 atm and at temperatures between 294 and 334 K yield mixtures of 3-chloro-l-butene and (E)-and (Z)-l-chloro-2-butene. The ratio of the product of putative l, &addition to those of 1, 4-addition is approximately unity with only the amount of (Z)-l-chloro-2-butene increasing from ca. 2% of the total reaction product mixture at the lower temperature to ca. 4% at the ...