A re??examination of the S0→ S1 excitation spectrum of dimethylaniline
RA Weersink, SC Wallace…
Index: Weersink, Robert A.; Wallace, Stephen C.; Gordon, Robert D. Journal of Chemical Physics, 1995 , vol. 103, # 22 p. 9530 - 9540
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Citation Number: 16
Abstract
A new assignment for the S0→ S1 transition of N, N??dimethylaniline (DMA) and related derivatives is presented. The low frequency bands and long Franck–Condon envelope observed in DMA??h 6 and DMA??d 6 are assigned to the coupled methyl torsion mode of the amino group, not to torsion of the amino substituent about the C–N bond. This new assignment is consistent with the change in frequency of the excitation bands upon ...
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