Chemical Communications

A novel allylic transfer reaction of chirally modified 2-borylbutadiene: synthesis of chiral homoallenyl alcohols

J Choi, B Lee, CM Yu

Index: Choi, Jihoon; Lee, Bobin; Yu, Chan-Mo Chemical Communications, 2011 , vol. 47, # 13 p. 3811 - 3813

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Citation Number: 12

Abstract

In light of widespread advances in synthetic methods for the synthesis of chiral substances, the allylic transfer reactions of carbonyl functionalities using chiral auxiliaries or catalysts led to significant developments in the area of asymmetric synthesis. A number of successful methodologies using stoichiometric amounts of chiral reagents and a catalytic amount of chiral Lewis acid or base have been developed and applied to organic synthesis. 8 Subsequent to early studies on ...

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