New synthetic approach to 1-azabicyclo [xy 0] alkane skeletons from β-enamino diesters derived from Meldrum's acid
…, JP Célérier, G Haviari, G Lhommet, H Dhimane…
Index: Haddad, Mansour; Celerier, Jean Pierre; Haviari, Gjergj; Lhommet, Gerard; Dhimane, Hamid; at al. Heterocycles, 1990 , vol. 31, # 7 p. 1251 - 1260
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Citation Number: 12
Abstract
Résumé/Abstract Two complementary methods for the synthesis of title compounds, namely, monodecarboxylating transesterification of β-enamino esters (I) followed by intramolecular cyclization, and direct cyclization of I under flash vacuum thermolysis conditions, have been elaborated. Azabicyclic compounds were stereospecifically converted to bicyclic β-amino alcohols by means of stereocontrolled carbon-carbon double bond catalytic ...
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[Celerier, J. P.; Haddad, M.; Saliou, C.; Lhommet, G. Tetrahedron, 1989 , vol. 45, # 19 p. 6161 - 6170]