Structure and stability of 2σ/1σ* three??electron??bonded radical cations from 1, n??bis (alkylthio) alkanes in aqueous solutions

E Anklam, KD Asmus, H Mohan

Index: Anklam, Elke Synthesis, 1987 , # 9 p. 841 - 843

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Citation Number: 19

Abstract

Abstract A large number of 1, n-bis (alkylthio) alkanes, R′ S (CH 2) n SR ″, was investigated by pulse radiolysis in aqueous solutions. The sulphur-centred radical cations, which were obtained on oxidation of the dithia compounds by· OH radicals, are stabilized via