Dipyrrinone imines: controlling self-association
P Ward, RR Chandler, MT Huggins
Index: Ward, Patrick; Chandler, Rebecca R.; Huggins, Michael T. Supramolecular Chemistry, 2013 , vol. 25, # 5 p. 286 - 291
Full Text: HTML
Citation Number: 0
Abstract
We report the synthesis of three new dipyrrinone imine analogues and the characterisation of their self-association properties. Based on vapour pressure osmometry and nuclear magnetic resonance studies, placing the imine functional group at C (9) of the dipyrrinone disrupts the native self-association of the dipyrrinone core in a manner that correlates with the conformational A-value of the imine N-substituent.
Related Articles:
A new convergent method for porphyrin synthesis based on a '3+ 1'condensation
[Boudif, Arezki; Momenteau, Michel Journal of the Chemical Society. Perkin Transactions 2, 1996 , vol. 1996, # 11 p. 1235 - 1242]