Hydrates and ammonium salts of 4-nitrobenzenesulfonic acid: supramolecular organization and its relation to proton conductivity

PY Barzilovich, KA Lyssenko, MY Antipin…

Index: Barzilovich; Lyssenko; Antipin; Aldoshin Russian Chemical Bulletin, 2011 , vol. 60, # 6 p. 1185 - 1195

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Citation Number: 3

Abstract

Abstract Structural features, the crystal packing, and the proton conductivity of a series of hydrates and ammonium salts of 4-nitrobenzenesulfonic acid were studied. It was shown that infinite cation associates containing the onium moiety are responsible for a substantial increase in the proton conductivity. The nature of the disorder in a series of crystals was investigated by performing X-ray diffraction studies at different temperatures. A new type of ...