Chemische Berichte

Tris??phenylmercapto??methyllithium Ein ungewöhnliches Carbenoid

D Seebach

Index: Seebach,D. Chemische Berichte, 1972 , vol. 105, p. 487 - 510

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Citation Number: 58

Abstract

Abstract Lösungen der Titelverbindung 4 in Tetrahydrofuran erhält man durch Metallierung von Trisphenylmercapto-methan, durch Lithium/SC 6 H 5-Austausch in Tetrakis- phenylmercapto-methan und durch „thiophile” Addition von Phenyllithium an Diphenyl- trithiocarbonat. Die Titelverbindung zersetzt sich erst oberhalb 20 in Tetrakis- phenylmercapto-äthylen (9), der Zerfall wird durch Lithiumthiophenolat abgebremst, durch ...

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