The Journal of Organic Chemistry

Organic disulfides and related substances. XXV. Thiocarbamoyl and imidocarbamoyl disulfides

L Field, JD Buckman

Index: Field,L.; Buckman,J.D. Journal of Organic Chemistry, 1968 , vol. 33, # 10 p. 3865 - 3871

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Citation Number: 21

Abstract

Thiolsulfonates (aryl, primary, or tertiary alkyl) thioalkylated dithiocarbamates (unsubstituted, N-methyl, N, N-dimethyl) to form unsymmetrical thiocarbamoyl disulfides in 48-88% yield; a promising synthesis of an ammonium alkanesulfinate resulted as a side issue. Dipotassium N-(p-toluenesulfony1) dithiocarbamate was dialkylated at sulfur by methyl sulfate but only monothioalkylated by a thiolsulfonate. An imidocarbamoyl disulfide was prepared from a ...