Journal of organometallic chemistry

Nickel (0) induzierte und katalysierte CC-verknüpfungen zwischen phenylisocyanat und vinylsubstituierten heteroaromaten

H Hoberg, D Guhl, P Betz

Index: Hoberg, Heinz; Guhl, Dieter; Betz, Peter Journal of Organometallic Chemistry, 1990 , vol. 387, # 2 p. 233 - 246

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Citation Number: 9

Abstract

Abstract Vinyl substituted heterocycles such as 2-vinylfuran (Ia) and 2-vinylpyridine (Ib) react with phenylisocyanate (II) in presence of (Lig) Ni 0 (Lig= TCP) to form the tricyclohexylphosphane-5-azanickelacyclopentan-4-one derivatives (V). The structures and properties of these metallacycles are described.