Tetrahedron letters
A novel degradative strategy for the synthesis of p-quinones.
JM Saa, J Morey, A Costa
Index: Saa, Jose M.; Morey, Jeronimo; Costa, Antonio Tetrahedron Letters, 1986 , vol. 27, # 42 p. 5125 - 5128
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Citation Number: 11
Abstract
Abstract p-Hydroxybenzylalcohols undergo Fremy's salt promoted degradative oxidation to give the corresponding p-benzoquinones. A novel strategy for the synthesis of p- benzoquinones based on the regioselective metalation of 2-methoxy-4-methoxymethyl phenols is presented.
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Metalation of phenols. Synthesis of benzoquinones by the oxidative degradation approach
[Saa, Jose M.; Llobera, Antonia; Garcia-Raso, Angel; Costa, Antonio; Deya, Pedro M. Journal of Organic Chemistry, 1988 , vol. 53, # 18 p. 4263 - 4273]