Reaction of carbonyl compounds with trialkylsilyl phenylselenide and tributylstannyl hydride under radical conditions
Y Nishiyama, H Kajimoto, K Kotani…
Index: Nishiyama, Yutaka; Kajimoto, Hiroyuki; Kotani, Kazuya; Nishida, Takuma; Sonoda, Noboru Journal of Organic Chemistry, 2002 , vol. 67, # 16 p. 5696 - 5700
Full Text: HTML
Citation Number: 7
Abstract
A novel method for the hydrosilylation of carbonyl compounds has been developed. When carbonyl compounds were allowed to react with trimethylsilyl phenylselenide and tributylstannyl hydride in the presence of a catalytic amount of AIBN as the radical initiator, hydrosilylation of the carbonyl compounds efficiently proceeded to give the corresponding silyl ethers in moderate to good yields. In the absence of carbonyl compounds, the ...
Related Articles:
[Khazaei, Ardeshir; Rostami, Amin; Mahboubifar, Marjan Journal of the Chinese Chemical Society, 2007 , vol. 54, # 2 p. 483 - 487]
[Wang, Huadong; Froehlich, Roland; Kehr, Gerald; Erker, Gerhard Chemical Communications, 2008 , # 45 p. 5966 - 5968]
[Brunet, Jean-Jacques; Besozzi, Denis; Caubere, Paul Synthesis, 1982 , # 9 p. 721 - 723]
[Akhlaghinia, Batool Phosphorus, Sulfur and Silicon and the Related Elements, 2009 , vol. 184, # 10 p. 2530 - 2535]
[Oskooie, Hossein A.; Heravi, Majid M.; Tehrani, Maryam H.; Behbahani, Farahnaz K.; Heravi, Omid M. Phosphorus, Sulfur and Silicon and the Related Elements, 2009 , vol. 184, # 7 p. 1729 - 1737]