Helvetica Chimica Acta

Eine stereospezifische Synthese von erythro??2??Amino??1, 3, 4??trihydroxy??butan

J Kiss, F Sirokman

Index: Kiss,J.; Sirokman,F. Helvetica Chimica Acta, 1960 , vol. 43, p. 334 - 338

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Citation Number: 5

Abstract

Abstract Das linksdrehende erythro-2-Amino-1, 3, 4-trihydroxy-butan wurde auf folgendem stereospezifischen Weg synthetisiert: Das aus dem trans-1, 4-Dibenzyloxy-2-buten (II) dargestellte trans-Epoxyd III gibt durch Ammonolyse dl-erythro-2-Amino-1, 3, 4-trihydroxy- butan-1, 4-dibenzyläther (IV), welcher mit L-Glutaminsäure gespalten wurde. Das durch Hydrogenolyse gebildete D-erythro-2-Amino-1, 3, 4-trihydroxybutan ist identisch mit dem ...

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