Tetrahedron letters

Trimethylsilyl chloride/tetramethylethylenediamine facilitated additions of organocopper reagents (RCu) to enones

CR Johnson, TJ Marren

Index: Johnson, Carl R.; Marren, Thomas J. Tetrahedron Letters, 1987 , vol. 28, # 1 p. 27 - 30

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Citation Number: 129

Abstract

... Printed in Great Britain Perqamon Journals Ltd. Trimethylsilyl Chloride/'I'etramethylethylene diamine Facilitated Additions of Organocopper Reagents (RCu) to Enones Carl R. Johnson* and Thomas J. Marren Department of Chemistry, Wayne State University, Detroit, Michigan 48202 Summary: Alkylcoppers (RCu) add readily in a conjugate fashion to enones in the presence of TMSCl and TMEDA to give high yields of trimethylsilyl enol ethers. ...