Novel 1, 5, 3-dithiazepanes: three-component synthesis, stereochemistry, and fungicidal activity

…, GR Khabibullina, IS Bushmarinov, LF Korzhova…

Index: Akhmetova; Murzakova; Tyumkina; Khabibullina; Bushmarinov; Korzhova; Galimzyanova Russian Chemical Bulletin, 2012 , vol. 61, # 11 p. 2140 - 2148 Izv. Akad. Nauk, Ser. Khim., 2012 , # 11 p. 2123 - 2131,9

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Citation Number: 12

Abstract

Abstract Three-component heterocyclization of hydrazine with formaldehyde and ethane-1, 2-dithiol gave previously unknown 3, 3′-bi (1, 5, 3-dithiazepane). Its stereochemistry was determined by X-ray diffraction. The reaction with higher aliphatic aldehydes RCHO (R= Me, Et, Pr n, and Bun) yielded 2, 4-dialkyl-3-alkylideneamino-1, 5, 3-dithiazepanes. The stereochemistry of the latter was determined by 1 H and 13 C NMR spectroscopy and ...