3-Diethylphosphonoacrolein diethylthioacetal anion (6*), a reagent for the conversion of aldehydes to α, β-unsaturated ketene dithioacetals and three-carbon …

G Jusr, P Potvin, GH Hakimelahi

Index: Just, George; Potvin, Pierre; Hakimelahi, Gholam Hosein Canadian Journal of Chemistry, 1980 , vol. 58, p. 2780 - 2783

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Abstract

GEORGE JUST, PIERRE POTVIN et GHOLAM HOSEIN HAKIMELAHI. Can. J. Chem. 58, 2780 (1980). On dkcrit une courte synthese du compose du titre, qui peut transformer les aldehydes en dith~oacttals de cktenes a,p-insatures, dont les sulfoxides conduisent aux aldehydes a$-insaturtes correspondantes. ... No synthesis of the title compound (6*) has ... All attempts to hydrolyse either compounds 8a,b ... Diethyl2,3-epoxyprop-1-ylphosphonate 1 (2) was smoothly to ...

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