Silver (I) ion catalyzed rearrangements of strained. sigma. bonds. XXIX. Influence of structural features on the course of transition metal catalyzed 1, 8-bishomocubane …
LA Paquette, RA Boggs, WB Farnham…
Index: Paquette,L.A. et al. Journal of the American Chemical Society, 1975 , vol. 97, # 5 p. 1112 - 1118
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Citation Number: 10
Abstract
Abstract: Evidence is presented that the rearrangements of several I, 8-bishomocubane derivatives by various Rh (1) and Pd (ll) catalysts are sensitive not only to the nature of the ligands attached to the metal but also to the level of substitution at the reaction site (C, and CS). Thus, the level of snoutane production increases in the order [Rh (NOR) C1] 2< Pdlz (PPh&< PdCIZ (PPh3) z< PdCI>(PhCN) 2 irrespective of the degree or nature of the ...
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