Ring-Opening Metathesis Polymerization with the Second Generation Hoveyda–Grubbs Catalyst: An Efficient Approach toward High-Purity Functionalized Macrocyclic …
A Blencowe, GG Qiao
Index: Blencowe, Anton; Qiao, Greg G. Journal of the American Chemical Society, 2013 , vol. 135, # 15 p. 5717 - 5725
Full Text: HTML
Citation Number: 13
Abstract
Herein, we present a facile and general strategy to prepare functionalized macrocyclic oligo (cyclooctene) s (cOCOEs) in high purity and high yield by exploiting the ring-opening metathesis polymerization (ROMP) intramolecular backbiting process with the commercially available second generation Hoveyda–Grubbs (HG2) catalyst. In the first instance, ROMP of 5-acetyloxycyclooct-1-ene (ACOE) followed by efficient quenching and removal of the ...
Related Articles:
[Khusnutdinov; Shchadneva; Khisamova; Dzhemilev Russian Journal of Organic Chemistry, 2011 , vol. 47, # 2 p. 155 - 160]
THEORETICAL, METHODOLOGICAL, AND GENERAL
[Cope; Wood Journal of the American Chemical Society, 1957 , vol. 79, p. 3885,3888 Full Text Show Details Cope; Johnson Journal of the American Chemical Society, 1957 , vol. 79, p. 3889,3891]