Tetrahedron Letters

Clay-supported reagents; III the intermediacy of nitrous esters in the oxidation of alcohols by clay-supported ferric nitrate.

A Cornélis, PY Herzé, P Laszlo

Index: Cornelis, Andre; Herze, Pierre-Yves; Laszlo, Pierre Tetrahedron Letters, 1982 , vol. 23, # 48 p. 5035 - 5038

Full Text: HTML

Citation Number: 31

Abstract

QUANTITATIVE conversion of alcohols into carbonyl compounds can be effected conveniently, under mild reaction conditions, using ferric nitrate impregnated on K 10 bentonlte clay. This reagent (" clayfen" for short) is obtained easily and cheaply from addltlon of the clay to a suspension of ferric nitrate in acetone and evaporation of the solvent To perform the oxldatlon, clayfen 1s added to a pentane or hexane solution of the alcohol, ...

Related Articles:

Dinuclear vanadium, copper, manganese and titanium complexes containing O, O, N-dichelating ligands: Synthesis, crystal structure and catalytic activity

[Hosseini-Monfared, Hassan; Asghari-Lalami, Nasim; Pazio, Aleksandra; Wozniak, Krzysztof; Janiak, Christoph Inorganica Chimica Acta, 2013 , vol. 406, p. 241 - 250]

Catalytic decomposition of 1, 3-diphenoxybenzene to monomeric cyclic compounds over palladium catalysts supported on acidic activated carbon aerogels

[Park, Hai Woong; Kim, Jeong Kwon; Hong, Ung Gi; Lee, Yoon Jae; Choi, Jung Ho; Bang, Yongju; Song, In Kyu Applied Catalysis A: General, 2013 , vol. 456, p. 59 - 66]

Epoxidation of alkenes with hydrogen peroxide in the presence of molybdenum oxide-tributyltin chloride on charcoal catalysts.

[Itoi, Yasushi; Inoue, Masami; Enomoto, Saburo; Watanabe, Yoshihiro Chemical and Pharmaceutical Bulletin, 1984 , vol. 32, # 2 p. 418 - 423]

Catalytic decomposition of 4-phenoxyphenol over Pd/XCs 2.5 H 0.5 PW 12 O 40/ACA (activated carbon aerogel)-SO 3 H (X= 10–30wt%) catalysts

[Park, Hai Woong; Kim, Jeong Kwon; Hong, Ung Gi; Lee, Yoon Jae; Song, Ji Hwan; Song, In Kyu Applied Catalysis A: General, 2013 , vol. 453, p. 287 - 294]

Catalytic alkane hydroxylation reaction with nickel (II) complexes supported by di-and triphenol ligands

[Nagataki, Takayuki; Itoh, Shinobu Chemistry Letters, 2007 , vol. 36, # 6 p. 748 - 749]

More Articles...