Journal of Organometallic Chemistry

Organoboranes: XV. A simple convenient procedure for the preparation of alkyldichloroboranes via hydroboration-redistribution

HC Brown, AB Levy

Index: Brown,H.C.; Levy,A.B. Journal of Organometallic Chemistry, 1972 , vol. 44, p. 233 - 236

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Citation Number: 1

Abstract

Abstract Trialkylboranes derived from terminal, cyclic and bicyclic olefins via hydroboration with 5 mole percent excess borane undergo ready redistribution with boron trichloride at 110 to give the corresponding alkyldichloroboranes, providing a convenient synthesis of such derivatives. On the other hand, trialkylboranes derived from internal olefins, such as 3- hexene, undergo this reaction more sluggishly and produce products in which the boron ...

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