Chemical communications

[VO (H2O) 5] H [PMo12O40]-catalyzed nitration of alkanes with nitric acid

K Yamaguchi, S Shinachi, N Mizuno

Index: Yamaguchi, Kazuya; Shinachi, Satoshi; Mizuno, Noritaka Chemical Communications, 2004 , # 4 p. 424 - 425

Full Text: HTML

Citation Number: 3

Abstract

Currently, nitration of lower alkanes such as propane is usually carried out using nitrogen dioxide or nitric acid under forced reaction conditions (523–673 K) because of the difficulty of activation of C–H bonds as well as nitrating agents. Under such conditions, alkanes undergo cleavage of the C–C bonds, resulting in formation of an undesirable mixture of lower alkanes and lower nitroalkanes. 5,6 In the presence of ozone at 195 K, nitrogen dioxide reacts with ...

Related Articles:

Dinuclear vanadium, copper, manganese and titanium complexes containing O, O, N-dichelating ligands: Synthesis, crystal structure and catalytic activity

[Hosseini-Monfared, Hassan; Asghari-Lalami, Nasim; Pazio, Aleksandra; Wozniak, Krzysztof; Janiak, Christoph Inorganica Chimica Acta, 2013 , vol. 406, p. 241 - 250]

Catalytic decomposition of 1, 3-diphenoxybenzene to monomeric cyclic compounds over palladium catalysts supported on acidic activated carbon aerogels

[Park, Hai Woong; Kim, Jeong Kwon; Hong, Ung Gi; Lee, Yoon Jae; Choi, Jung Ho; Bang, Yongju; Song, In Kyu Applied Catalysis A: General, 2013 , vol. 456, p. 59 - 66]

Epoxidation of alkenes with hydrogen peroxide in the presence of molybdenum oxide-tributyltin chloride on charcoal catalysts.

[Itoi, Yasushi; Inoue, Masami; Enomoto, Saburo; Watanabe, Yoshihiro Chemical and Pharmaceutical Bulletin, 1984 , vol. 32, # 2 p. 418 - 423]

Catalytic decomposition of 4-phenoxyphenol over Pd/XCs 2.5 H 0.5 PW 12 O 40/ACA (activated carbon aerogel)-SO 3 H (X= 10–30wt%) catalysts

[Park, Hai Woong; Kim, Jeong Kwon; Hong, Ung Gi; Lee, Yoon Jae; Song, Ji Hwan; Song, In Kyu Applied Catalysis A: General, 2013 , vol. 453, p. 287 - 294]

Catalytic alkane hydroxylation reaction with nickel (II) complexes supported by di-and triphenol ligands

[Nagataki, Takayuki; Itoh, Shinobu Chemistry Letters, 2007 , vol. 36, # 6 p. 748 - 749]

More Articles...