Helvetica chimica acta

Rhodium (II)??Catalyzed Decomposition of β, γ??Unsaturated Diazo Compounds

S Motallebi, P Müller

Index: Motallebi; Muller Helvetica Chimica Acta, 1993 , vol. 76, # 8 p. 2803 - 2813

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Citation Number: 10

Abstract

Abstract The Rh II-catalyzed decomposition of β, γ-unsaturated diazo ketones 1 in the presence of MeOH leads via vinylogous Wolff rearrangement to γ, δ-unsaturated esters 6 (Schemes 1 and 2). A modest asymmetric induction is achieved when the reaction is carried