Dissociation or cyclization: Options for a triad of radicals released from oxime carbamates

RT McBurney, JC Walton

Index: McBurney, Roy T.; Walton, John C. Journal of the American Chemical Society, 2013 , vol. 135, # 19 p. 7349 - 7354

Full Text: HTML

Citation Number: 15

Abstract

A set of oxime carbamates having N-alkyl and N, N-dialkyl substituents were prepared via carbonyldiimidazole intermediates. It was shown by EPR spectroscopy that they underwent clean homolysis of their N–O bonds upon UV photolysis. During photolysis of ...