Spectral Properties of Medium-and Large-ring Carbocyclic Compounds: α-Bromoketones, Enol Acetates and Unsaturated Ketones

NJ Leonard, FH Owens

Index: Leonard; Owens Journal of the American Chemical Society, 1958 , vol. 80, p. 6039,6044

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Citation Number: 48

Abstract

A study of the spectra of medium-and large-ring carbocyclic 2-bromoketones, ketone-enol acetates and unsaturated ketones has provided interesting information concerning their stereochemistry. In particular, the infrared shifts observed for the carbonyl maximum in going from the cyclic ketone to the corresponding 2-bromoketone indicate that the average conformations of 2-bromocyclooctanone, 2-bromocyclononanone and 2- ...