The Journal of Organic Chemistry

Oxidation with metal oxides. III. Oxidation of diamines and hydrazines with manganese dioxide

I Bhatnagar, MV George

Index: Bhatnagar,I.; George,M.V. Journal of Organic Chemistry, 1968 , vol. 33, # 6 p. 2407 - 2411

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Citation Number: 46

Abstract

+ Phenylenediamine and p-phenylenediamine, on oxidation with manganese dioxide, gave the corresponding diaminoazo compounds. Under similar conditions, 2, 2'-diaminobiphenyl gave dibenzopyridazine, whereas o, o'-diaminobiphenyl sulfide gave a linear azo compound. The oxidation of N-phenyl-p-phenylenediamine and N, N'-diphenyl-p- phenylenediamine gave N-phenyl-p-benzoquinone monoimine and N, N'-diphenyl-p- ...