“1, 3-Shifts” in Rearrangements of 3, 4, 4-Trimethyl-2-pentyl Derivatives1

WH Saunders Jr, GL Carges

Index: Saunders,W.H.; Carges,G.L. Journal of the American Chemical Society, 1960 , vol. 82, p. 3582 - 3585

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Citation Number: 4

Abstract

CHa CH2 CH3 IX syntheses gave a single pure product, but the olefins could be separated from each other by gas chromatography and the peaks in the chromatograms identified. For example, the common product in dehydrations of I and IV must be 111. The predominant (ca. 807,) product from dehydration of VI1 was assumed to be VIII. No unequivocal synthesis of VI was undertaken, but it did not correspond to any other reasonable possibility and has ...