Complete Oxidation of Sugars by 1-Methylphenylhydrazine. The Alkazones

OL Chapman, WJ Welstead, TJ Murphy…

Index: Chapman,O.L. et al. Journal of the American Chemical Society, 1964 , vol. 86, p. 732 - 733

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Citation Number: 9

Abstract

(3) L. Mester, J. Am. Chem. SOL., 77, 4301 (1955).(4) G. Henseke and H. Kohler, Ann., 614, 105 (1958).(5) An alternate explanation is that anion formation at C-3 in the phenylosazones is inhibited by formation of delocalized anions by ionization of the NH bonds. Formation of i is requisite to further oxidation of the osazone,