Russian Journal of Organic Chemistry

Chemistry of Dioxacycloalkanes: VII. Synthesis and Properties of Substituted 1, 3-Dioxolanes Derived from Carbocyclic Aldehydes

AK Kerimov

Index: Kerimov Russian Journal of Organic Chemistry, 2001 , vol. 37, # 1 p. 136 - 140

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Abstract

Abstract Reactions of 3-cyclohexenecarbaldehyde, 6-methyl-3-cyclohexenecarbaldehyde, bicyclo [2.2. 1]-hept-5-ene-endo-2-carbaldehyde, benzaldehyde with 1, 2-propanediol, 3- chloro-1, 2-propanediol gavethe corresponding 2, 4-substituted 1, 3-dioxolanes. Their reactions with peroxyacetic acid, bromine, dichloro-carbene, and nucleophiles were studied. The effect of the substituents in the diol and aldehyde on their relative reactivity is ...