Chiral synthesis via organoboranes. 10. Preparation of. alpha.-chiral acyclic ketones of exceptionally high enantiomeric excess from optically pure borinic esters
HC Brown, M Srebnik, RK Bakshi…
Index: Brown,H.C.; Srebnik,M.; Bakshi,R.K. Journal of the American Chemical Society, 1987 , vol. 109, p. 5420
Full Text: HTML
Citation Number: 44
Abstract
Abstract: Optically pure borinic esters, R* R'BOR”, obtained from optically pure boronic esters, R* B (OR'') 2 and organolithium reagents, were treated with dichloromethyl methyl ether (DCME) in the presence of lithium tert-butoxide to give, after oxidation with hydrogen ...
Related Articles:
A mild, efficient approach to 3-acylfurans: a short synthesis of perilla ketone
[Bailey Synthesis, 1991 , # 3 p. 242 - 243]
[Katritzky, Alan R.; Lang, Hengyuan; Wang, Zuoquan; Zhang, Zhongxing; Song, Huimin Journal of Organic Chemistry, 1995 , vol. 60, # 23 p. 7619 - 7624]
[Katritzky, Alan R.; Lang, Hengyuan; Wang, Zuoquan; Zhang, Zhongxing; Song, Huimin Journal of Organic Chemistry, 1995 , vol. 60, # 23 p. 7619 - 7624]
[Katritzky, Alan R.; Lang, Hengyuan; Wang, Zuoquan; Zhang, Zhongxing; Song, Huimin Journal of Organic Chemistry, 1995 , vol. 60, # 23 p. 7619 - 7624]
[Katritzky, Alan R.; Lang, Hengyuan; Wang, Zuoquan; Zhang, Zhongxing; Song, Huimin Journal of Organic Chemistry, 1995 , vol. 60, # 23 p. 7619 - 7624]