Iron??Catalyzed π??Activated C–O Ether Bond Cleavage with C–C and C–H Bond Formation
…, YH Guan, LA Fu, H Lv, K Guo, HB Zhu
Index: Fan, Xiaohui; Cui, Xiao-Meng; Guan, Yong-Hong; Fu, Lin-An; Lv, Hao; Guo, Kun; Zhu, Hong-Bo European Journal of Organic Chemistry, 2014 , vol. 2014, # 3 p. 498 - 501
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Citation Number: 8
Abstract
Abstract A novel and efficient allylic alkylation reaction between π-activated ethers and allylsilane was realized under mild conditions through iron (III)-catalyzed C inline image–O ether bond cleavage. The present protocol provides an attractive approach for the construction of sp 3–sp 3 C–C bonds and can be potentially applied for the selective reduction of benzyl and allyl ethers to their corresponding hydrocarbon compounds by ...
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