Tetrahedron letters

Silver ion perturbation of olefin photochemistry

H Morrison, C Koviak

Index: Morrison, Harry; Koviak, Carol Tetrahedron Letters, 1986 , vol. 27, # 24 p. 2711 - 2714

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Citation Number: 5

Abstract

Earlier reports of three products fron the myrcene photolysis are in error; we observe four by capillary gc, with the newly identified product being 6,6-dimethyl-2- methylenebicyclo[3.2.0]heptane , recently reported as being formed by CuOTf photocatalysis J. Org. Chem., 49 (1984), p. 4322 This product appears to have been buried under the p-pinene peak under previously employed gc conditions, and is formed in about a 1:2 ratio with the p-pinene. ... We have also noted ...

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