Synthesis, characterization and catalytic activity of new aminomethyldiphosphine–Pd (II) complexes for Suzuki cross-coupling reaction
M Keleş, MK Yılmaz
Index: Keles, Mustafa; Yilmaz, Mustafa Kemal Applied Organometallic Chemistry, 2014 , vol. 28, # 2 p. 91 - 94
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Citation Number: 3
Abstract
A new range of CF3-substituted aminomethyldiphosphine (P―C―N) ligands ((C6H5) 2PCH2) 2NR (R=―C6H4 (2-CF3)(1a),―C6H4 (3-CF3)(1b) has been synthesized from 2- (trifluoromethyl) aniline and 3-(trifluoromethyl) aniline with diphenylphosphine. The aminomethyldiphosphine ligands were reacted with Pd (cod) Cl2 to give corresponding metal complexes, PdLCl2 (2a, 2b). The aminomethyldiphosphine–palladium compounds ...
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