Alkoxy-and amidocarbonylation of functionalised aryl and heteroaryl halides catalysed by a Bedford palladacycle and dppf: a comparison with the primary Pd (ii) …
IJS Fairlamb, S Grant, P McCormack, J Whittall
Index: Fairlamb, Ian J. S.; Grant, Stephanie; McCormack, Peter; Whittall, John Dalton Transactions, 2007 , # 8 p. 859 - 865
Full Text: HTML
Citation Number: 16
Abstract
The versatility of a Bedford-type palladacycle 1, namely [{Pd (µ-Cl){κ2-P, CP (OC6H2-2, 4- tBu2)(OC6H3-2, 4-tBu2) 2}} 2], as a primary Pd source, in combination with the ligand bis-1, 1′-(diphenylphosphino) ferrocene (dppf) has been established in carbonylation reactions of aryl and heteroaryl bromides with methanol, piperidine and related nucleophiles. Palladacycle 1 has been compared with other primary Pd sources, eg (PhCN) 2PdCl2 and ...
Related Articles:
Facile preparation of amides from carboxylic acids and amines with ion-supported Ph 3 P
[Kawagoe, Yuhsuke; Moriyama, Katsuhiko; Togo, Hideo Tetrahedron, 2013 , vol. 69, # 19 p. 3971 - 3977]
Radical mediated-direct conversion of aldehydes into acid bromides
[Kang, Dong Ho; Joo, Tae Young; Chavasiri, Warinthorn; Jang, Doo Ok Tetrahedron Letters, 2007 , vol. 48, # 2 p. 285 - 287]
[Tran, Ba L.; Li, Bijie; Driess, Matthias; Hartwig, John F. Journal of the American Chemical Society, 2014 , vol. 136, # 6 p. 2555 - 2563]
[Do, Hien-Quang; Bachman, Shoshana; Bissember, Alex C.; Peters, Jonas C.; Fu, Gregory C. Journal of the American Chemical Society, 2014 , vol. 136, # 5 p. 2162 - 2167]
[Basavanag, Unnamatla M. V.; Dos Santos, Aurelie; El Kaim, Laurent; Gamez-Montano, Rocio; Grimaud, Laurence Angewandte Chemie - International Edition, 2013 , vol. 52, # 28 p. 7194 - 7197 Angew. Chem., 2013 , vol. 125, # 28 p. 7335 - 7338,4]