Russian journal of general chemistry

Reactions of titanium alcoholates Ti (OR) 4 (R= n-Bu, t-Bu) with tertiary organic and organometallic hydroperoxides

LP Stepovik, MV Gulenova

Index: Stepovik; Gulenova Russian Journal of General Chemistry, 2006 , vol. 76, # 2 p. 235 - 244

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Citation Number: 2

Abstract

Abstract tert-Butyl and cumyl hydroperoxides in the reactions with Ti (OR) 4 are reduced to alcohols with the evolution of oxygen via formation of titanium-containing peroxides and trioxides. The pathways of the reactions of Ti (OR) 4 with triphenylelement hydroperoxides R 3 EOOH (E= C, Si, Ge) depend on element E and on the structure of R; the reactions involve the rearrangement of the peroxides, and with (n-BuO) 4 Ti the alkoxy group is oxidized ...