Electrochemical reduction of unsymmetrically substituted diphenyliodonium salts at mercury cathodes in dimethylformamide
MS Mubarak, DG Peters
Index: Mubarak, Mohammad S.; Peters, Dennis G. Journal of Organic Chemistry, 1985 , vol. 50, # 5 p. 673 - 677
Full Text: HTML
Citation Number: 10
Abstract
A study has been made of the electrochemistry of five unsymmetrically substituted diphenyliodonium salts at mercury cathodes in dimethylformamide containing tetramethylammonium perchlorate. Polarograms indicate that the iodonium cations undergo reduction in three stages:(1) one-electron reduction to yield either (a) iodobenzene and a substituted phenylmercury radical or (b) a substituted iodobenzene and a phenylmercury ...
Related Articles:
Facile syntheses of homoleptic diarylmercurials via arylboronic acids
[Partyka, David V.; Gray, Thomas G. Journal of Organometallic Chemistry, 2009 , vol. 694, # 2 p. 213 - 218]
[Mubarak, Mohammad S.; Karras, Louis L.; Murcia, Noel S.; Bart, John C.; Stemple, Joseph Z.; Peters, Dennis G. Journal of Organic Chemistry, 1990 , vol. 55, # 3 p. 1065 - 1070]