The Reaction of β-Nitroalcohols and Reactive Aldehydes

J Yoshimura, T Iida, M Funabashi

Index: Yoshimura,J. et al. Bulletin of the Chemical Society of Japan, 1970 , vol. 43, p. 3887 - 3891

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Citation Number: 4

Abstract

Condensation of acyclic or cyclic β-nitroalcohols with aldehydes was examined. In the case of non-protected 1-deoxy-1-C-nitro-D-glycitols and benzaldehyde, products caused by aldehyde-exchange reaction were obtained. However, the reaction of 2-methoxy-1- nitropentane or non-protected 2-nitrocyclohexanol and reactive aldehydes (formaldehyde, acetaldehyde and n-butyl glyoxylate) in the presence of sodium hydrogencarbonate gave ...