Tetrahedron Letters

Gas phase substituent effects. Stabilities of 1-aryl-2, 2, 2-trifluoroethyl cations

M Hishima, H Inoue, M Fujio, Y Tsuno

Index: Hishima, Masaaki; Inoue, Hiroki; Fujio, Mizue; Tsuno, Yuho Tetrahedron Letters, 1990 , vol. 31, # 5 p. 685 - 688

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Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Gas-phase stabilities of 1-aryl-2,2,2-trifluoroethyl cations were determined based on chloride-transfer equilibria. The substituent effect was analyzed based on the LArSR Eq., giving a remarkably high r of 1.53 and a ϱ of −14.6. ... The substituent effect for the gas-phase ...

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