Australian Journal of Chemistry

Experiments directed towards the synthesis of anthracyclinones. XXIV. Homochiral intermediates for vineomycin syntheses

MG Pausler, PS Rutledge

Index: Pausler, M. Gabrielle; Rutledge, Peter S. Australian Journal of Chemistry, 1994 , vol. 47, # 12 p. 2149 - 2160

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Citation Number: 3

Abstract

Abstract Homochiral intermediates suitable for the synthesis of vineomycins have been prepared by a titanium-mediated addition of an enolate of (-)-menthyl acetate to the furano ketones (12) and (13). The absolute configurations of the menthyl butanoates (14) and (15)