Tetrahedron Letters

Synthesis of a new polypyridinic highly conjugated ligand with electron-acceptor properties

R Dı́az, O Reyes, A Francois, AM Leiva, B Loeb

Index: Diaz, Ramiro; Reyes, Oscar; Francois, Angelica; Leiva, Ana Maria; Loeb, Barbara Tetrahedron Letters, 2001 , vol. 42, # 37 p. 6463 - 6467

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Citation Number: 26

Abstract

A new acceptor polypyridinic ligand functionalized with a quinone fragment is reported. The ligand, dipyrido [3, 2-a: 2′, 3′-c]-benzo [3, 4]-phenazine-11, 16-quinone, Nqphen, was synthesized by condensation of 1, 10-phenanthroline-5, 6-dione and 2, 3-diamino-1, 4- naphthoquinone. The syntheses of two rhenium complexes with this ligand are also reported.

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