Journal of the American Chemical Society

The Reactions of Trimethylene Oxide with Mercaptans, Thiophenol and Some Inorganic Sulfur Compounds1

S Searles

Index: Searles Journal of the American Chemical Society, 1951 , vol. 73, p. 4515

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Citation Number: 17

Abstract

Trimethylene oxide is cleaved by sulfur anions in the same manner as is ethylene oxide although at a much slower rate. The reaction of thiophenol and aliphatic mercaptans proceeds smoothly in alkaline solution to give good yields of 3-hydroxypropyl sulfides, whereas no reaction occurs with tetrahydrofuran. The reactions of trimethylene oxide are strongly catalyzed by acids. A kinetic study of the reaction with aqueous sodium thiosulfate ...