The Combination of 1-Butyl-3-methylimidazolium Bromide and Trichloro (trifluoromethanesulfonato) titanium (IV) as a New Protocol for the Synthesis of Aryl …
J Noei, AR Khosropour, A Mirjafari
Index: Noei, Jalil; Khosropour, Ahmad Reza; Mirjafari, Arsalan Bulletin of the Korean Chemical Society, 2012 , vol. 33, # 6 p. 2102 - 2104
Full Text: HTML
Citation Number: 4
Abstract
Nitriles are one of the most important precursors in organic synthesis. These compounds are used for the preparation of esters, 1 amides, 1, 2 carboxylic acids, 1, 3 amines 1, 4 and thioamides. 5 Nitriles have also found widespread application in preparation of heterocycles as tetrazoles. 6 The classical method for the synthesis of alkyl nitriles is the reaction of alkyl halides with highly toxic metal cyanide via a nucleophilic pathway. However, this reaction ...
Related Articles:
[Ushijima, Sousuke; Moriyama, Katsuhiko; Togo, Hideo Tetrahedron, 2011 , vol. 67, # 5 p. 958 - 964]
Direct transformation of N, N-disubstituted amides and isopropyl esters to nitriles
[Suzuki, Yusuke; Yoshino, Takumi; Moriyama, Katsuhiko; Togo, Hideo Tetrahedron, 2011 , vol. 67, # 21 p. 3809 - 3814]
Copper-catalyzed dehydration of primary amides to nitriles
[Enthaler, Stephan; Weidauer, Maik Catalysis Letters, 2011 , vol. 141, # 8 p. 1079 - 1085]
Direct transformation of N, N-disubstituted amides and isopropyl esters to nitriles
[Suzuki, Yusuke; Yoshino, Takumi; Moriyama, Katsuhiko; Togo, Hideo Tetrahedron, 2011 , vol. 67, # 21 p. 3809 - 3814]
Facile transformation of esters to nitriles
[Suzuki, Yusuke; Moriyama, Katsuhiko; Togo, Hideo Tetrahedron, 2011 , vol. 67, # 41 p. 7956 - 7962]