Enantioselective Total Synthesis of (-)-Clavosolide A and B

JB Son, SN Kim, NY Kim, M Hwang…

Index: Son, Jung Beom; Kim, Si Nae; Kim, Na Yeong; Hwang, Min-Ho; Lee, Wonsun; Lee, Duck Hyung Bulletin of the Korean Chemical Society, 2010 , vol. 31, # 3 p. 653 - 663

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Citation Number: 6

Abstract

Enantioselective total synthesis of (-)-clavosolide A and B was reported in full including the synthesis of proposed structure of (-)-clavosoldie A (1), revised structure of (-)-clavosoldie A (5), and revised structure of (-)-clavosoldie B (6). The relative and absolute stereochemistries of the natural products were confirmed unambiguously by comparing the optical rotation values and 1H and 13C NMR spectra of them. Key Words: ...